Material made from crab shells may replace plastic packaging

Researchers at the Georgia Institute of Technology have created a material derived from crab shells and tree fibres which they believe has the potential to replace the flexible plastic packaging used to keep food fresh.

The new material is made by spraying multiple layers of chitin from crab shells and cellulose from trees to form a flexible film similar to plastic packaging film.

“The main benchmark that we compare it to is PET, or polyethylene terephthalate, one of the most common petroleum-based materials in the transparent packaging you see in vending machines and soft drink bottles,” said J. Carson Meredith, a professor at Georgia Tech’s School of Chemical and Biomolecular Engineering.

“Our material showed up to a 67% reduction in oxygen permeability over some forms of PET, which means it could in theory keep foods fresher longer.”

The researchers said that cellulose, which comes from plants, is the planet’s most common natural biopolymer, followed next by chitin, which is found in shellfish, insects and fungi. 

The team devised a method to create a film by suspending cellulose and chitin nanofibres in water and spraying them onto a surface in alternating layers. Once fully dried, the material is flexible, strong, transparent and compostable.

Meredith added: “We had been looking at cellulose nanocrystals for several years and exploring ways to improve those for use in lightweight composites as well as food packaging, because of the huge market opportunity for renewable and compostable packaging, and how important food packaging overall is going to be as the population continues to grow.”

The team had been looking into chitin for an unrelated reason when they wondered if it might have use in food packaging.

“We recognised that because the chitin nanofibres are positively charged, and the cellulose nanocrystals are negatively charged, they might work well as alternating layers in coatings because they would form a nice interface between them,” Meredith said.

Packaging meant to preserve food needs to prevent oxygen from passing through. Part of the reason the new material improves upon conventional plastic packaging as a gas barrier is because of the crystalline structure of the film.

“It’s difficult for a gas molecule to penetrate a solid crystal, because it has to disrupt the crystal structure,” Meredith said. “Something like PET on the other hand has a significant amount of amorphous or non-crystalline content, so there are more paths easier for a small gas molecule to find its way through.”

To make the new material eventually competitive with flexible packaging film on cost, a manufacturing process that maximizes economy of scale will need to be developed.

Additionally, while industrial processes to mass produce cellulose are mature, methods to produce chitin are still in their infancy, the researchers said. More research is also needed to improve the material’s ability to block water vapour.